Issue 11, 2005

A simple method for the α-oxygenation of aldehydes

Abstract

A mild, efficient and general method for the chemospecific α-oxygenation of aldehydes is described. Treatment of a series of aldehydes with N-tert-butyl-O-benzoyl hydroxylamine hydrochloride gives the corresponding α-oxygenated carbonyl via a proposed pericyclic rearrangement process.

Graphical abstract: A simple method for the α-oxygenation of aldehydes

Article information

Article type
Communication
Submitted
02 Dec 2004
Accepted
23 Dec 2004
First published
24 Jan 2005

Chem. Commun., 2005, 1478-1480

A simple method for the α-oxygenation of aldehydes

C. S. Beshara, A. Hall, R. L. Jenkins, T. C. Jones, R. T. Parry, S. P. Thomas and N. C. O. Tomkinson, Chem. Commun., 2005, 1478 DOI: 10.1039/B418101H

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