Issue 11, 2005
From the journal:

Chemical Communications

Alkynes as activators in the nickel-catalysed addition of organoboronates to aldehydes†

Go Takahashi,a   Eiji Shirakawa,*b   Teruhisa Tsuchimotoa  and  Yusuke Kawakamia  

* Corresponding authors

a Graduate School of Materials Science, Japan Advanced Institute of Science and Technology, Tatsunokuchi, Ishikawa, Japan

b Department of Chemistry, Graduate School of Science, Kyoto University, Sakyo, Kyoto, Japan
E-mail: shirakawa@kuchem.kyoto-u.ac.jp
Fax: 81 75 753 3988

Abstract

Alkynes act not as substrates but as co-catalysts in the presence of a nickel catalyst, an organoboronate and an aldehyde to promote the addition reaction between the substrates in combination with H2O.

Graphical abstract: Alkynes as activators in the nickel-catalysed addition of organoboronates to aldehydes

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Article information

DOI
https://doi.org/10.1039/B417353H
Article type
Communication
Submitted
17 Nov 2004
Accepted
23 Dec 2004
First published
25 Jan 2005

Chem. Commun., 2005, 1459-1461

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Alkynes as activators in the nickel-catalysed addition of organoboronates to aldehydes

G. Takahashi, E. Shirakawa, T. Tsuchimoto and Y. Kawakami, Chem. Commun., 2005, 1459 DOI: 10.1039/B417353H

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