Issue 11, 2005
From the journal:

Chemical Communications

Coordination chemistry of the bis(trifluoromethylsulfonyl)imide anion: molecular interactions in room temperature ionic liquids

D. Bridget Williams,†a   Michael E. Stoll,a   Brian L. Scott,b   David A. Costaa  and  Warren J. Oldham, Jr.*b  

* Corresponding authors

a Nuclear Materials Technology Division (NMT-15), Los Alamos National Laboratory, Los Alamos, New Mexico 87545, USA

b Chemistry Division, Los Alamos National Laboratory, Los Alamos, New Mexico 87545, USA
E-mail: woldham@lanl.gov

Abstract

Room temperature ionic liquids composed of bis(trifluoromethylsulfonyl)imide anions and 1,3-ethylmethylimidazolium (EMI) cations are shown to stabilize monomeric ligand deficient transition metal complexes via four distinct binding modes: monodentate nitrogen or oxygen coordination and/or bidentate oxygen–oxygen′ or nitrogen–oxygen coordination (η1–N, η1–O, η2–O,O′ and η2–N,O).

Graphical abstract: Coordination chemistry of the bis(trifluoromethylsulfonyl)imide anion: molecular interactions in room temperature ionic liquids

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Article information

DOI
https://doi.org/10.1039/B416830E
Article type
Communication
Submitted
04 Nov 2004
Accepted
23 Dec 2004
First published
21 Jan 2005

Chem. Commun., 2005, 1438-1440

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Coordination chemistry of the bis(trifluoromethylsulfonyl)imide anion: molecular interactions in room temperature ionic liquids

D. B. Williams, M. E. Stoll, B. L. Scott, D. A. Costa and W. J. Oldham, Jr., Chem. Commun., 2005, 1438 DOI: 10.1039/B416830E

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