Issue 11, 2005
From the journal:

Chemical Communications

Formation, stability, and reactivity of a mononuclear nonheme oxoiron(iv) complex in aqueous solution†

Chivukula V. Sastri,a   Mi Sook Seo,a   Mi Joo Park,a   Kwan Mook Kima  and  Wonwoo Nam*a  

* Corresponding authors

a Department of Chemistry, Division of Nano Sciences, and Center for Biomimetic Systems, Ewha Womens University, Seoul 120-750, Korea
E-mail: wwnam@ewha.ac.kr
Fax: +82 2 3277 4441
Tel: +82 2 3277 2392

Abstract

A mononuclear nonheme oxoiron(IV) complex bearing a pentadentate N5 ligand was prepared in aqueous solution; the pH dependence of its stability and reactivities was reported along with the mechanistic details of sulfide oxidation by the oxoiron(IV) species.

Graphical abstract: Formation, stability, and reactivity of a mononuclear nonheme oxoiron(iv) complex in aqueous solution

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Article information

DOI
https://doi.org/10.1039/B415507F
Article type
Communication
Submitted
06 Oct 2004
Accepted
05 Jan 2005
First published
27 Jan 2005

Chem. Commun., 2005, 1405-1407

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Formation, stability, and reactivity of a mononuclear nonheme oxoiron(IV) complex in aqueous solution

C. V. Sastri, M. Sook Seo, M. Joo Park, K. Mook Kim and W. Nam, Chem. Commun., 2005, 1405 DOI: 10.1039/B415507F

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