Issue 22, 2005
From the journal:

Chemical Communications

Nano-dimensions for the pyrogallol[4]arene cavity†

Gareth W. V. Cave,‡a   Matthew C. Ferrarellia  and  Jerry L. Atwood*a  

* Corresponding authors

a 125, Chemistry, University of Missouri-Columbia, 601 South College Avenue, Columbia, USA
E-mail: AtwoodJ@missouri.edu
Fax: +1(573)8848374
Tel: +1(573)8828374

Abstract

The cup-like cavity of pyrogallol[4]arenes has been deepened by the addition of four hydrogen bonded bipyridine molecules to the upper-rim of the calixarene, enabling the extended cup-like molecules to stack inside one another and consequently trap and completely enshroud a single guest molecule within the 250 Å3 cavitand formed between two of these stacked “nano-cups”.

Graphical abstract: Nano-dimensions for the pyrogallol[4]arene cavity

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Article information

DOI
https://doi.org/10.1039/B413829E
Article type
Communication
Submitted
08 Sep 2004
Accepted
17 Mar 2005
First published
18 Apr 2005

Chem. Commun., 2005, 2787-2789

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Nano-dimensions for the pyrogallol[4]arene cavity

G. W. V. Cave, M. C. Ferrarelli and J. L. Atwood, Chem. Commun., 2005, 2787 DOI: 10.1039/B413829E

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