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Issue 1, 2005
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C2 C70F38 is aromatic, contains three planar hexagons, and has equatorial addends

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Abstract

Single crystal X-ray analysis shows the main (C2) isomer of C70F38 to contain three planar delocalised aromatic hexagons (two equivalent and one centred on the C2 axis), together with seven C[double bond, length as m-dash]C bonds (three pairs and one straddling the C2 axis); C70F38 is the first high addition level [70]fullerene derivative to be fully characterised, is the first to have equatorial addends, and is calculated to have high stability.

Graphical abstract: C 2 C70F38 is aromatic, contains three planar hexagons, and has equatorial addends

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Article information


Submitted
16 Aug 2004
Accepted
21 Sep 2004
First published
19 Nov 2004

Chem. Commun., 2005, 75-77
Article type
Communication

C 2 C70F38 is aromatic, contains three planar hexagons, and has equatorial addends

P. B. Hitchcock, A. G. Avent, N. Martsinovich, P. A. Troshin and R. Taylor, Chem. Commun., 2005, 75
DOI: 10.1039/B412599A

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