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Issue 1, 2005
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Synthesis and structural characterization of highly chlorinated C70, C70Cl28

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Abstract

Chlorination of [70]fullerene with SbCl5, VCl4 or PCl5 yielded C70Cl28 comprising three isomers, all containing four isolated benzenoid rings in the fullerene cage. This demonstrates, for the first time for C70 derivatives, a stabilization effect due to planar aromaticity.

Graphical abstract: Synthesis and structural characterization of highly chlorinated C70, C70Cl28

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Publication details

The article was received on 12 Aug 2004, accepted on 15 Oct 2004 and first published on 19 Nov 2004


Article type: Communication
DOI: 10.1039/B412448K
Chem. Commun., 2005, 72-74

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    Synthesis and structural characterization of highly chlorinated C70, C70Cl28

    S. I. Troyanov, N. B. Shustova, I. N. Ioffe, A. P. Turnbull and E. Kemnitz, Chem. Commun., 2005, 72
    DOI: 10.1039/B412448K

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