Coupling of alkynols and a phenyl group to a novel η5-dihydronaphthalenide ligand on a ruthenium template

Jadranka Čubrilo; Rainer F. Winter; Dietrich Gudat

doi:10.1039/B412052C

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Coupling of alkynols and a phenyl group to a novel η⁵-dihydronaphthalenide ligand on a ruthenium template†

Jadranka Čubrilo,^a Rainer F. Winter*^a and Dietrich Gudat^a

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* Corresponding authors

^a Institut für Anorganische Chemie der Universität Stuttgart, Pfaffenwaldring 55, Stuttgart, Germany
E-mail: winter@iac.uni-stuttgart.de
Fax: +49 711 685 4165

Abstract

We report the highly selective assembly of unprecedented η⁵-1-methylene-1,2-dihydronaphthalenide ligands from the stoichiometric coupling of a phenyl group and two equivalents of disubstituted propargylic alcohols; in this reaction, tetraphenylborate acts as a phenylating agent.

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Article information

DOI: https://doi.org/10.1039/B412052C
Article type: Communication
Submitted: 05 Aug 2004
Accepted: 23 Sep 2004
First published: 02 Dec 2004

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Chem. Commun., 2005, 510-512

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Coupling of alkynols and a phenyl group to a novel η⁵-dihydronaphthalenide ligand on a ruthenium template

J. Čubrilo, R. F. Winter and D. Gudat, Chem. Commun., 2005, 510 DOI: 10.1039/B412052C

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