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Issue 1, 2005
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A novel {FeI–FeII–FeII–FeI} iron thiolate carbonyl assembly which electrocatalyses hydrogen evolution

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Abstract

A novel tetra-iron thiolate carbonyl assembly is described in which two dithiolate tetracarbonyl di-iron centres with a ‘butterfly’ configuration of the {2Fe3S}-cores are fused by two bridging thiolates which form a central planar 2Fe2S unit and comprise the first example of a chain of four metal–metal bonded iron atoms supported by a bridging sulfur framework; the assembly electrocatalyses hydrogen evolution.

Graphical abstract: A novel {Fe–Fe–Fe–Fe} iron thiolate carbonyl assembly which electrocatalyses hydrogen evolution

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Publication details

The article was received on 29 Jul 2004, accepted on 24 Sep 2004 and first published on 11 Nov 2004


Article type: Communication
DOI: 10.1039/B411559G
Chem. Commun., 2005, 133-135

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    A novel {FeI–FeII–FeII–FeI} iron thiolate carbonyl assembly which electrocatalyses hydrogen evolution

    C. Tard, X. Liu, D. L. Hughes and C. J. Pickett, Chem. Commun., 2005, 133
    DOI: 10.1039/B411559G

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