Issue 24, 2004
From the journal:

Chemical Communications

Stereochemistry of contiguous cyclopropane formation from cascade cyclization of a skipped dienyl homoallyl triflate

Christopher M. Lincoln,a   James D. White*a  and  Alexandre F. T. Yokochia  

* Corresponding authors

a Department of Chemistry, Oregon State University, Corvallis, Oregon, USA
E-mail: james.white@orst.edu
Fax: 541-737-2660
Tel: 541-737-2173

Abstract

Solvolysis of asymmetric homoallylic triflates bearing a terminal stannyl substituent gives disubstituted cyclopropanes and bicyclopropanes bearing differentiated termini in high enantiopurity.

Graphical abstract: Stereochemistry of contiguous cyclopropane formation from cascade cyclization of a skipped dienyl homoallyl triflate

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Article information

DOI
https://doi.org/10.1039/B412811G
Article type
Communication
Submitted
20 Aug 2004
Accepted
29 Sep 2004
First published
28 Oct 2004

Chem. Commun., 2004, 2846-2847

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Stereochemistry of contiguous cyclopropane formation from cascade cyclization of a skipped dienyl homoallyl triflate

C. M. Lincoln, J. D. White and A. F. T. Yokochi, Chem. Commun., 2004, 2846 DOI: 10.1039/B412811G

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