Issue 22, 2004
From the journal:

Chemical Communications

Lanthanide(iii) complexes of a pyridine N-oxide analogue of DOTA: exclusive M isomer formation induced by a six-membered chelate ring†

Miloslav Polášek,a   Jakub Rudovský,a   Petr Hermann,*a   Ivan Lukeš,a   Luce Vander Elstb  and  Robert N. Mullerb  

* Corresponding authors

a Department of Inorganic Chemistry, Universita Karlova, Hlavova 2030, 128 40 Prague 2, Czech Republic
E-mail: petrh@natur.cuni.cz
Fax: +420-221951253
Tel: +420-221951263

b NMR Laboratory, Department of Organic Chemistry, University of Mons-Hainaut, Avenue du champ de Mars 24, B-7000 Mons, Belgium

Abstract

The presence of a six-membered chelate ring involving a pyridine N-oxide moiety induces exclusive M isomer formation throughout the whole lanthanide series endowed with a fast water exchange in the case of the Gd(III) complex.

Graphical abstract: Lanthanide(iii) complexes of a pyridine N-oxide analogue of DOTA: exclusive M isomer formation induced by a six-membered chelate ring

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Article information

DOI
https://doi.org/10.1039/B409996F
Article type
Communication
Submitted
02 Jul 2004
Accepted
20 Aug 2004
First published
01 Oct 2004

Chem. Commun., 2004, 2602-2603

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Lanthanide(III) complexes of a pyridine N-oxide analogue of DOTA: exclusive M isomer formation induced by a six-membered chelate ring

M. Polášek, J. Rudovský, P. Hermann, I. Lukeš, L. V. Elst and R. N. Muller, Chem. Commun., 2004, 2602 DOI: 10.1039/B409996F

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