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Issue 19, 2004
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A very large Rh–Rh bond shortening on excitation of the [Rh2(1,8-diisocyano-p-menthane)4]2+ ion by time-resolved synchrotron X-ray diffraction

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Abstract

A very large Rh–Rh contraction of ∼0.85 Å occurs on excitation of the [Rh2(1,8-diisocyano-p-menthane)4]2+ ion to its triplet state.

Graphical abstract: A very large Rh–Rh bond shortening on excitation of the [Rh2(1,8-diisocyano-p-menthane)4]2+ ion by time-resolved synchrotron X-ray diffraction

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Publication details

The article was received on 24 Jun 2004, accepted on 29 Jul 2004 and first published on 19 Aug 2004


Article type: Communication
DOI: 10.1039/B409463H
Citation: Chem. Commun., 2004,0, 2144-2145

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    A very large Rh–Rh bond shortening on excitation of the [Rh2(1,8-diisocyano-p-menthane)4]2+ ion by time-resolved synchrotron X-ray diffraction

    P. Coppens, O. Gerlits, I. I. Vorontsov, A. Yu. Kovalevsky, Y. Chen, T. Graber, M. Gembicky and I. V. Novozhilova, Chem. Commun., 2004, 0, 2144
    DOI: 10.1039/B409463H

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