Issue 19, 2004
From the journal:

Chemical Communications

Isolation and structural characterization of an optically active intermediate in the oxidative addition of methyl iodide on a rhodium(i) centre†

Angelino Doppiu,a   Ulli Englerta  and  Albrecht Salzer*a  

* Corresponding authors

a Institut für Anorganische Chemie, RWTH Aachen, Prof.-Pirlet-Straße 1, D-52056 Aachen, Germany
E-mail: albrecht.salzer@ac.rwth-aachen.de
Fax: +49 241 8092644
Tel: +49 241 8094646

Abstract

The optically pure cationic complex (S,SRh)-[Rh(η5-C5H4CH2CH(Ph)PPh2-κP)(η2-CH2CH2)(CH3)][I] is the first example of a key intermediate in the oxidative addition reaction of methyl iodide on a rhodium(I) centre which has been structurally characterized by X-ray diffraction.

Graphical abstract: Isolation and structural characterization of an optically active intermediate in the oxidative addition of methyl iodide on a rhodium(i) centre

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/B409134E
Article type
Communication
Submitted
17 Jun 2004
Accepted
26 Jul 2004
First published
25 Aug 2004

Chem. Commun., 2004, 2166-2167

Permissions

Request permissions

Isolation and structural characterization of an optically active intermediate in the oxidative addition of methyl iodide on a rhodium(I) centre

A. Doppiu, U. Englert and A. Salzer, Chem. Commun., 2004, 2166 DOI: 10.1039/B409134E

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements