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Issue 12, 2004

Supertetrahedral decametallic Ni(ii) clusters directed by μ6-tris-alkoxides

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Abstract

We report the syntheses, structures and magnetic properties of two decametallic Ni(II) clusters with unprecedented supertetrahedral cores, stabilised by the (hitherto unobserved) μ6-coordination modes of the tris-alkoxides {MeC(CH2O)3}3− and {C6H9O3}3−.

Graphical abstract: Supertetrahedral decametallic Ni(ii) clusters directed by μ6-tris-alkoxides

Supplementary files

Article information


Submitted
16 Mar 2004
Accepted
29 Apr 2004
First published
17 May 2004

Chem. Commun., 2004, 1418-1419
Article type
Communication

Supertetrahedral decametallic Ni(II) clusters directed by μ6-tris-alkoxides

R. Shaw, I. S. Tidmarsh, R. H. Laye, B. Breeze, M. Helliwell, E. K. Brechin, S. L. Heath, M. Murrie, S. Ochsenbein, H. Güdel and E. J. L. McInnes, Chem. Commun., 2004, 1418 DOI: 10.1039/B403876B

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