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Issue 11, 2004
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First cation radical salt of a tetrathiafulvalene–based phosphine metal complex

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Abstract

Electrocrystallization of (o-P2)Mo(CO)4, where o-P2 is the tetrathiafulvalene-based chelating diphosphine o-Me2TTF-(PPh2)2, in the presence of the Linquist anion Mo6O192− affords a 2:1 salt, formulated as [(o-P2)Mo(CO)4]2[Mo6O19], with a Heisenberg spin chain magnetic behaviour.

Graphical abstract: First cation radical salt of a tetrathiafulvalene–based phosphine metal complex

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Article information


Submitted
01 Mar 2004
Accepted
08 Apr 2004
First published
05 May 2004

Chem. Commun., 2004, 1300-1301
Article type
Communication

First cation radical salt of a tetrathiafulvalene–based phosphine metal complex

N. Avarvari and M. Fourmigué, Chem. Commun., 2004, 1300
DOI: 10.1039/B403168G

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