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Issue 11, 2004
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Dynamic kinetic resolution: an efficient route to anti α-amino-β-hydroxy estersvia Ru-SYNPHOS® catalyzed hydrogenation

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Abstract

The Ru(II)-catalyzed hydrogenation of α-amino-β-keto esters as their hydrochloride salts affords preparation of the corresponding anti α-amino-β-hydroxy esters under mild conditions with high diastereoselectivities and enantioselectivities via dynamic kinetic resolution.

Graphical abstract: Dynamic kinetic resolution: an efficient route to anti α-amino-β-hydroxy esters via Ru-SYNPHOS® catalyzed hydrogenation

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Supplementary files

Article information


Submitted
03 Feb 2004
Accepted
31 Mar 2004
First published
06 May 2004

Chem. Commun., 2004, 1296-1297
Article type
Communication

Dynamic kinetic resolution: an efficient route to anti α-amino-β-hydroxy esters via Ru-SYNPHOS® catalyzed hydrogenation

C. Mordant, P. Dünkelmann, V. Ratovelomanana-Vidal and J. Genet, Chem. Commun., 2004, 1296
DOI: 10.1039/B401631A

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