A novel 2D net-like supramolecular polymer constructed from Ln6Cu24 node and trans-Cu(Gly)2 bridge

Jian-Jun Zhang; Sheng-Qing Xia; Tian-Lu Sheng; Sheng-Min Hu; Guido Leibeling; Franc Meyer; Xin-Tao Wu; Sheng-Chang Xiang; Rui-Biao Fu

doi:10.1039/B400447G

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A novel 2D net-like supramolecular polymer constructed from Ln₆Cu₂₄ node and trans-Cu(Gly)₂ bridge†

Jian-Jun Zhang,^a Sheng-Qing Xia,^a Tian-Lu Sheng,^a Sheng-Min Hu,^a Guido Leibeling,^b Franc Meyer,^b Xin-Tao Wu,*^a Sheng-Chang Xiang^a and Rui-Biao Fu^a

Author affiliations

* Corresponding authors

^a State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, P. R. China
E-mail: wxt@ms.fjirsm.ac.cn

^b Institut fuer Anorganische Chemie der George-August-Universitaet Goettingen, Tammannstrasse 4, 37077 Goettingen, Germany

Abstract

A 2D net-like lanthanide-copper heterometallic supramolecular network {Ln₆Cu₂₇} 1 was synthesized with Ln₆Cu₂₄ octahedral cluster as the node and trans-Cu(glycinato)₂ group as the linker. The compound represents the first example of 2D polymer with high-nuclear 3d–4f heterometallic cluster as the node.

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Article information

DOI: https://doi.org/10.1039/B400447G
Article type: Communication
Submitted: 12 Jan 2004
Accepted: 30 Mar 2004
First published: 14 Apr 2004

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Chem. Commun., 2004, 1186-1187

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A novel 2D net-like supramolecular polymer constructed from Ln₆Cu₂₄ node and trans-Cu(Gly)₂ bridge

J. Zhang, S. Xia, T. Sheng, S. Hu, G. Leibeling, F. Meyer, X. Wu, S. Xiang and R. Fu, Chem. Commun., 2004, 1186 DOI: 10.1039/B400447G

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