Issue 5, 2004

A direct meta-lithiation route to 1,3-disubstituted ferrocenes

Abstract

Ferrocenyl sulfides afford meta-lithiation products with up to 94% regioselectivity on reaction with s-BuLi; the resulting 1,3-disubstituted ferrocenes can then be reacted with a variety of electrophiles.

Graphical abstract: A direct meta-lithiation route to 1,3-disubstituted ferrocenes

Article information

Article type
Communication
Submitted
13 Nov 2003
Accepted
09 Jan 2004
First published
10 Feb 2004

Chem. Commun., 2004, 598-599

A direct meta-lithiation route to 1,3-disubstituted ferrocenes

C. Pichon, B. Odell and J. M. Brown, Chem. Commun., 2004, 598 DOI: 10.1039/B314641C

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