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Issue 4, 2004
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Amine elimination synthesis of a titanium(IV) N-heterocyclic carbene complex with short intramolecular Cl⋯Ccarbene contacts

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Abstract

The reaction of 1,3-dimesitylimidazolium chloride with Ti(NMe2)4 results in the 1,3-dimesitylimadazol-2-ylidene complex of Ti(NMe2)2Cl2 (3); the X-ray crystal structure of 3 evidences short intramolecular Cl⋯Ccarbene contacts.

Graphical abstract: Amine elimination synthesis of a titanium(IV) N-heterocyclic carbene complex with short intramolecular Cl⋯Ccarbene contacts

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Publication details

The article was received on 13 Nov 2003, accepted on 27 Nov 2003 and first published on 15 Jan 2004


Article type: Communication
DOI: 10.1039/B314558A
Citation: Chem. Commun., 2004,0, 360-361
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    Amine elimination synthesis of a titanium(IV) N-heterocyclic carbene complex with short intramolecular Cl⋯Ccarbene contacts

    P. Shukla, J. A. Johnson, D. Vidovic, A. H. Cowley and C. D. Abernethy, Chem. Commun., 2004, 0, 360
    DOI: 10.1039/B314558A

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