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Issue 4, 2004
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Discovery and evaluation of highly active imidotitanium ethylene polymerisation catalysts using high throughput catalyst screening

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Abstract

A family of ca. 50 imidotitanium precatalysts [Ti(NR)(Me3[9]aneN3)Cl2] (R = alkyl or aryl; Me3[9]aneN3 = 1,4,7-trimethyltriazacyclononane) were prepared in good yields using semi-automated procedures; high-throughput screening techniques identified seven highly active ethylene polymerisation precatalysts with activities in the range ca. 3 400 to 10 000 kg(PE) mol−1 h−1 bar−1.

Graphical abstract: Discovery and evaluation of highly active imidotitanium ethylene polymerisation catalysts using high throughput catalyst screening

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Supplementary files

Article information


Submitted
03 Nov 2003
Accepted
02 Dec 2003
First published
14 Jan 2004

Chem. Commun., 2004, 434-435
Article type
Communication

Discovery and evaluation of highly active imidotitanium ethylene polymerisation catalysts using high throughput catalyst screening

N. Adams, H. J. Arts, P. D. Bolton, D. Cowell, S. R. Dubberley, Nic. Friederichs, C. M. Grant, M. Kranenburg, A. J. Sealey, B. Wang, P. J. Wilson, A. R. Cowley, P. Mountford and M. Schröder, Chem. Commun., 2004, 434
DOI: 10.1039/B313921B

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