Highly diastereoselective formation of C2-symmetric bis-thioglycoside Pd(II) complexes: the role of the exo anomeric effect

Noureddine Khiar; Cristina S. Araújo; Bélen Suárez; Eleuterio Alvarez; Inmaculada Fernández

doi:10.1039/B313798H

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

Highly diastereoselective formation of C₂-symmetric bis-thioglycoside Pd(ii) complexes: the role of the exo anomeric effect†

Noureddine Khiar,*^a Cristina S. Araújo,^a Bélen Suárez,^a Eleuterio Alvarez^a and Inmaculada Fernández*^b

Author affiliations

* Corresponding authors

^a Instituto de Investigaciones Químicas, C.S.I.C-Universidad de Sevilla, c/. Américo Vespucio, s/n., Isla de la Cartuja, 41092 Sevilla, Spain
E-mail: khiar@cica.es
Fax: +34 954460565

^b Departamento de Química Orgánica y Farmacéutica, Facultad de Farmacia, Universidad de Sevilla, 41012 Sevilla, Spain
E-mail: inmaff@us.es
Fax: +34 954556737

Abstract

Treatment of several C₂ symmetric bis-thioglycosides with Pd(CH₃CN)₂Cl₂ always leads to a single diastereomeric Pd(II) complex as a consequence of the exo-anomeric effect.

Download options Please wait...

Supplementary files

Article information

DOI: https://doi.org/10.1039/B313798H
Article type: Communication
Submitted: 31 Oct 2003
Accepted: 23 Dec 2003
First published: 16 Feb 2004

Download Citation

Chem. Commun., 2004, 714-715

Permissions

Request permissions

Highly diastereoselective formation of C₂-symmetric bis-thioglycoside Pd(II) complexes: the role of the exo anomeric effect

N. Khiar, C. S. Araújo, B. Suárez, E. Alvarez and I. Fernández, Chem. Commun., 2004, 714 DOI: 10.1039/B313798H

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Chemical Communications