Issue 1, 2004
From the journal:

Chemical Communications

A new synthesis of 1,3-dihydrobenzo[1,2]oxasiloles by a novel rearrangement of a pentavalent silicon intermediate

George Bashiardes,*a   Vanessa Chaussebourg,a   Géraldine Laverdana  and  Jacques Porneta  

* Corresponding authors

a Departement de Chimie, Université de Poitiers, SFA-UMR 6514, 40 avenue du Recteur Pineau, 86022 Poitiers cedex, France
E-mail: george.bashiardes@univ-poitiers.fr

Abstract

A new synthesis of benzo[1,2]oxasiloles is described, wherein an unprecedented intramolecular allylic transposition takes place probably involving a pentavalent silicon intermediate.

Graphical abstract: A new synthesis of 1,3-dihydrobenzo[1,2]oxasiloles by a novel rearrangement of a pentavalent silicon intermediate

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Article information

DOI
https://doi.org/10.1039/B311804E
Article type
Communication
Submitted
24 Sep 2003
Accepted
10 Nov 2003
First published
26 Nov 2003

Chem. Commun., 2004, 122-123

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A new synthesis of 1,3-dihydrobenzo[1,2]oxasiloles by a novel rearrangement of a pentavalent silicon intermediate

G. Bashiardes, V. Chaussebourg, G. Laverdan and J. Pornet, Chem. Commun., 2004, 122 DOI: 10.1039/B311804E

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