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Issue 1, 2004

Regio- and enantioselective iridium-catalysed allylic aminations and alkylations of dienyl esters

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Abstract

Regio- and enantioselective iridium-catalysed allylic aminations and alkylations of dienyl substrates are presented; using phosphorus amidite L1 as ligand, aminations provided ee values of up to 97% and alkylations of up to 90%.

Graphical abstract: Regio- and enantioselective iridium-catalysed allylic aminations and alkylations of dienyl esters

Supplementary files

Article information


Submitted
18 Sep 2003
Accepted
16 Oct 2003
First published
07 Nov 2003

Chem. Commun., 2004, 116-117
Article type
Communication

Regio- and enantioselective iridium-catalysed allylic aminations and alkylations of dienyl esters

G. Lipowsky and G. Helmchen, Chem. Commun., 2004, 116 DOI: 10.1039/B311502J

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