Issue 23, 2003
From the journal:

Chemical Communications

Regioselective uncatalysed hydrophosphination of alkenes: a facile route to P-alkylated phosphine derivatives

David Mimeau,ab   Olivier Delacroixb  and  Annie-Claude Gaumont*b  

* Corresponding authors

a Laboratoire de Synthèse et d'Electrosynthèse Organique, UMR CNRS 6510 Université de Rennes, Campus de Beaulieu, 35042 Rennes, France

b Laboratoire de Chimie Moléculaire et Thio-organique, UMR CNRS 6507, ENSI-CAEN, Université de Caen, 6 bd du Maréchal Juin, 14050 Caen, France
E-mail: annie-claude.gaumont@ismra.fr
Fax: +33 2 31 45 28 77
Tel: +33 2 31 45 28 73

Abstract

The synthesis of alkylarylphosphines is easily carried out by hydrophosphination of unactivated alkenes under mild thermal activation; gram scale amounts of products can be prepared by this simple methodology.

Graphical abstract: Regioselective uncatalysed hydrophosphination of alkenes: a facile route to P-alkylated phosphine derivatives

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Article information

DOI
https://doi.org/10.1039/B311892D
Article type
Communication
Submitted
25 Sep 2003
Accepted
13 Oct 2003
First published
29 Oct 2003

Chem. Commun., 2003, 2928-2929

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Regioselective uncatalysed hydrophosphination of alkenes: a facile route to P-alkylated phosphine derivatives

D. Mimeau, O. Delacroix and A. Gaumont, Chem. Commun., 2003, 2928 DOI: 10.1039/B311892D

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