Issue 21, 2003
From the journal:

Chemical Communications

Synthesis, characterization and catalytic activity of a Wilkinson's type metal-organic–polyoxometalate hybrid compound

Itsik Bar-Nahuma  and  Ronny Neumann*a  

* Corresponding authors

a Department of Organic Chemistry, Weizmann Institute of Science, Rehovot, Israel, 76100
E-mail: Ronny.Neumann@weizmann.ac.il
Fax: +972-8-9344142
Tel: +972-8-9343354

Abstract

A metal-organic–polyoxometalate hybrid compound with two functional centers consisting of a rhodium(I)bis(diphenylphospine) unit connected through two alkylene bridging groups to a lacunary Keggin type polyoxometalate was synthesized and used as an effective, recyclable hydrogenation catalyst in monophasic and aqueous biphasic reaction modes.

Graphical abstract: Synthesis, characterization and catalytic activity of a Wilkinson's type metal-organic–polyoxometalate hybrid compound

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Article information

DOI
https://doi.org/10.1039/B310236J
Article type
Communication
Submitted
27 Aug 2003
Accepted
10 Sep 2003
First published
29 Sep 2003

Chem. Commun., 2003, 2690-2691

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Synthesis, characterization and catalytic activity of a Wilkinson's type metal-organic–polyoxometalate hybrid compound

I. Bar-Nahum and R. Neumann, Chem. Commun., 2003, 2690 DOI: 10.1039/B310236J

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