Structure and electronic properties of an asymmetric thiolate-bridged binuclear complex: a model for the active site of acetyl CoA synthase†
Abstract
The asymmetric binuclear complex [(dppe)Ni(μ-‘S, S’)Ni(L)](PF6)2
[L =
(N, N′-diethyl-3,7-diazanonane-1,9-dithiolato)2−] shows a reversible one-electron