Issue 21, 2003
From the journal:

Chemical Communications

The generation and trapping of organozinc carbenoids from N-diethoxymethyl amides: a new amidocyclopropanation reaction

Guillaume Bégis,a   David Cladingboelb  and  William B. Motherwell*a  

* Corresponding authors

a Department of Chemistry, Christopher Ingold Laboratories, University College London, 20 Gordon Street, London, UK
E-mail: w.b.motherwell@ucl.ac.uk

b AstraZeneca R&D Charnwood, Bakewell Road, Loughborough, UK

Abstract

Amidocyclopropanes are readily prepared by reaction of N-diethoxymethyl amides with alkenes in the presence of zinc amagalm, zinc chloride and chlorotrimethylsilane.

Graphical abstract: The generation and trapping of organozinc carbenoids from N-diethoxymethyl amides: a new amidocyclopropanation reaction

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Article information

DOI
https://doi.org/10.1039/B309887G
Article type
Communication
Submitted
18 Aug 2003
Accepted
12 Sep 2003
First published
03 Oct 2003

Chem. Commun., 2003, 2656-2657

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The generation and trapping of organozinc carbenoids from N-diethoxymethyl amides: a new amidocyclopropanation reaction

G. Bégis, D. Cladingboel and W. B. Motherwell, Chem. Commun., 2003, 2656 DOI: 10.1039/B309887G

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