Issue 16, 2003
From the journal:

Chemical Communications

Direct formation of an organonitrogen compound from a molybdenum nitrido species

Huub Henderickx,a   Gerard Kwakkenbos,a   Alexander Peters,*a   Jan van der Spoela  and  Koen de Vriesa  

* Corresponding authors

a DSM Research, P.O. Box 18, 6160MD Geleen, The Netherlands
E-mail: alexander.peters@dsm.com

Abstract

The molybdenum nitrido complex 15NMo[N(R)Ar]3 (where R = C(CD3)2CH3, Ar = 3,5-C6H3Me2) reacted with the anhydride of trifluoroacetic acid at room temperature to afford the correspondent organonitrogen compound in almost quantitative yield without the necessity of using additional reagents to achieve the C–N coupling.

Graphical abstract: Direct formation of an organonitrogen compound from a molybdenum nitrido species

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Article information

DOI
https://doi.org/10.1039/B305774G
Article type
Communication
Submitted
23 May 2003
Accepted
25 Jun 2003
First published
09 Jul 2003

Chem. Commun., 2003, 2050-2051

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Direct formation of an organonitrogen compound from a molybdenum nitrido species

H. Henderickx, G. Kwakkenbos, A. Peters, J. V. D. Spoel and K. de Vries, Chem. Commun., 2003, 2050 DOI: 10.1039/B305774G

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