Issue 15, 2003
From the journal:

Chemical Communications

A zeolite–enzyme combination for biphasic dynamic kinetic resolution of benzylic alcohols

Stijn Wuyts,a   Karolien De Temmerman,a   Dirk De Vosa  and  Pierre Jacobs*a  

* Corresponding authors

a Centre for Surface Chemistry and Catalysis, KULeuven, Kasteelpark Arenberg 23, 3001 Leuven, Belgium
E-mail: pierre.jacobs@agr.kuleuven.ac.be
Fax: 32 1632 1998
Tel: 32 1632 1595

Abstract

Acid zeolites like H-Beta are efficient heterogeneous catalysts for racemization of benzylic alcohols in water; by combination of the racemization with an enzymatic kinetic resolution in a two-phase system, enantiomerically pure esters were obtained in high yield via a dynamic kinetic resolution.

Graphical abstract: A zeolite–enzyme combination for biphasic dynamic kinetic resolution of benzylic alcohols

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Article information

DOI
https://doi.org/10.1039/B305120J
Article type
Communication
Submitted
07 May 2003
Accepted
12 Jun 2003
First published
27 Jun 2003

Chem. Commun., 2003, 1928-1929

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A zeolite–enzyme combination for biphasic dynamic kinetic resolution of benzylic alcohols

S. Wuyts, K. De Temmerman, D. De Vos and P. Jacobs, Chem. Commun., 2003, 1928 DOI: 10.1039/B305120J

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