Issue 16, 2003

Dithiocarbamyl-substituted diphosphanylmethanide complexes of manganese(i): a new type of ambivalent metalloligands

Abstract

The diphosphanylmethanide complex [Mn(CO)4{(PPh2)2C–H}] promotes S–S bond breaking in tetramethylthiuram disulfide affording [Mn(CO)4{(PPh2)2C–S–C(S)NMe2}] (2), which proved to be a valuable host for binding cations through the methanide carbon atom and the thiocarbonyl group, allowing the controlled synthesis of heterometallic compounds.

Graphical abstract: Dithiocarbamyl-substituted diphosphanylmethanide complexes of manganese(i): a new type of ambivalent metalloligands

Supplementary files

Article information

Article type
Communication
Submitted
07 May 2003
Accepted
19 Jun 2003
First published
03 Jul 2003

Chem. Commun., 2003, 2028-2029

Dithiocarbamyl-substituted diphosphanylmethanide complexes of manganese(I): a new type of ambivalent metalloligands

J. Ruiz, R. Quesada, V. Riera, S. García-Granda and M. Rosario Díaz, Chem. Commun., 2003, 2028 DOI: 10.1039/B305045A

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