Issue 13, 2003
From the journal:

Chemical Communications

A highly deformed iron(ii) low-spin phthalocyanine which shows two MLCT transitions beyond the Q-band

Takamitsu Fukuda,a   Shigetsugu Hommaa  and  Nagao Kobayashi*a  

* Corresponding authors

a Department of Chemistry, Graduate School of Science, Tohoku University, Sendai 980-8578, Japan
E-mail: nagaok@mail.cc.tohoku.ac.jp
Fax: (+81)-22-217-7719
Tel: (+81)-22-217-7719

Abstract

A highly deformed [1,4,8,11,15,18,22,25-octaphenylphthalo-cyaninato(2-)]iron(II) has been synthesized, and found to show absorption bands which may be assigned to metal-to-ligand charge transfer (MLCT) transitions in the near-IR region beyond the Q-band in pyridine, due to lowering of molecular symmetry to D2d from D4h symmetry of normal metallophthalocyanines.

Graphical abstract: A highly deformed iron(ii) low-spin phthalocyanine which shows two MLCT transitions beyond the Q-band

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Article information

DOI
https://doi.org/10.1039/B303991A
Article type
Communication
Submitted
11 Apr 2003
Accepted
14 May 2003
First published
03 Jun 2003

Chem. Commun., 2003, 1574-1575

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A highly deformed iron(II) low-spin phthalocyanine which shows two MLCT transitions beyond the Q-band

T. Fukuda, S. Homma and N. Kobayashi, Chem. Commun., 2003, 1574 DOI: 10.1039/B303991A

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