Issue 6, 2003
From the journal:

Chemical Communications

Covalent crosslinking of 1-D photonic crystals of microporous Si by hydrosilylation and ring-opening metathesis polymerization

Myeong Sik Yoon,a   Kyo Han Ahn,*a   Ronnie W. Cheung,b   Honglae Sohn,b   Jamie R. Link,b   Frédérique Cuninb  and  Michael J. Sailor*b  

* Corresponding authors

a Department of Chemistry and Center for Integrated Molecular Systems, Division of Molecular and Life Science, Pohang University of Science & Technology, San 31 Hyoja-dong, Pohang 790-784, Republic of Korea
E-mail: ahn@postech.ac.kr
Fax: +(82) 54-279-3399
Tel: +(82) 54-279-2105

b Department of Chemistry and Biochemistry, The University of California, 9500 Gillman Drive, San Diego, CA 92039-0358, USA
E-mail: msailor@ucsd.edu
Fax: 858 534 5383
Tel: 858 534 8188

Abstract

Free-standing porous Si multilayer dielectric mirrors, prepared by electrochemical etching of crystalline Si, are treated with a ruthenium ring-opening metathesis polymerization (ROMP) catalyst followed by norbornene to produce flexible, stable composite materials in which poly(norbornene) is covalently attached to the porous Si matrix.

Graphical abstract: Covalent crosslinking of 1-D photonic crystals of microporous Si by hydrosilylation and ring-opening metathesis polymerization

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Article information

DOI
https://doi.org/10.1039/B300937H
Article type
Communication
Submitted
23 Jan 2003
Accepted
12 Feb 2003
First published
24 Feb 2003

Chem. Commun., 2003, 680-681

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Covalent crosslinking of 1-D photonic crystals of microporous Si by hydrosilylation and ring-opening metathesis polymerization

M. S. Yoon, K. H. Ahn, R. W. Cheung, H. Sohn, J. R. Link, F. Cunin and M. J. Sailor, Chem. Commun., 2003, 680 DOI: 10.1039/B300937H

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