Issue 4, 2003
From the journal:

Chemical Communications

Formal radical cyclization onto benzene rings—a general method proceeding via cross-conjugated dienones

Derrick L. J. Clive,*a   Stephen P. Fletchera  and  (in part) Mingzhao Zhua  

* Corresponding authors

a Chemistry Department, University of Alberta, Edmonton, Alberta, Canada
E-mail: derrick.clive@ualberta.ca

Abstract

Cross-conjugated dienones of type 5 (X = I), which are readily available from phenols, undergo radical cyclization (5 → 6 → 7), and the products are easily aromatized (7 → 8), giving substances that are formally derived by radical cyclization onto a benzene ring (cf.eqn. (1)).

Graphical abstract: Formal radical cyclization onto benzene rings—a general method proceeding via cross-conjugated dienones

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Article information

DOI
https://doi.org/10.1039/B212223E
Article type
Communication
Submitted
10 Dec 2002
Accepted
02 Jan 2003
First published
20 Jan 2003

Chem. Commun., 2003, 526-527

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Formal radical cyclization onto benzene rings—a general method proceeding via cross-conjugated dienones

D. L. J. Clive, S. P. Fletcher and (. P. M. Zhu, Chem. Commun., 2003, 526 DOI: 10.1039/B212223E

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