Issue 4, 2003
From the journal:

Chemical Communications

Aqueous organometallic reactions of rhodium porphyrins: equilibrium thermodynamics†

Xuefeng Fu,a   Leah Basickesa  and  Bradford B. Wayland*a  

* Corresponding authors

a Department of Chemistry, University of Pennsylvania, Philadelphia, PA 19104-6323, USA
E-mail: wayland@sas.upenn.edu
Fax: 215573-6743
Tel: 215898 6366

Abstract

The reactivity and equilibrium thermodynamic studies of tetra-p-sulfonatophenyl porphyrin rhodium hydride ([(TSPP)Rh–D]−4) with CO, aldehydes and olefins that produce formyl, α-hydroxyalkyl and alkyl complexes have been explored in water and compared with the related reactions in non-aqueous media.

Graphical abstract: Aqueous organometallic reactions of rhodium porphyrins: equilibrium thermodynamics

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Article information

DOI
https://doi.org/10.1039/B212027E
Article type
Communication
Submitted
05 Dec 2002
Accepted
06 Jan 2003
First published
17 Jan 2003

Chem. Commun., 2003, 520-521

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Aqueous organometallic reactions of rhodium porphyrins: equilibrium thermodynamics

X. Fu, L. Basickes and B. B. Wayland, Chem. Commun., 2003, 520 DOI: 10.1039/B212027E

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