Issue 3, 2003
From the journal:

Chemical Communications

C–H Activation of imidazolium salts by Pt(0) at ambient temperature: synthesis of hydrido platinum bis(carbene) compounds

Marcel A. Duin,a   Nicolas D. Clement,b   Kingsley J. Cavell*b  and  Cornelis J. Elsevier*a  

* Corresponding authors

a Institute of Molecular Chemistry, Organometallic and Coordination Chemistry, University of Amsterdam, Nieuwe Achtergracht 166, 1018 WV, Amsterdam, The Netherlands
E-mail: elsevier@science.uva.nl
Fax: 0031 (0)205256456
Tel: 0031 (0)205255653

b Department of Chemistry, Cardiff University, PO Box 912, Cardiff, Wales
E-mail: cavellkj@cf.ac.uk
Fax: +44 (0)29 2087 5899
Tel: +44 (0)29 2087 5899

Abstract

A zerovalent platinum(carbene) complex with two monoalkene ligands, which is able to activate C–H bonds of imidazolium salts at room temperature to yield isolable hydrido platinum(II) bis(carbene) compounds, has been synthesised for the first time.

Graphical abstract: C–H Activation of imidazolium salts by Pt(0) at ambient temperature: synthesis of hydrido platinum bis(carbene) compounds

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Article information

DOI
https://doi.org/10.1039/B211235C
Article type
Communication
Submitted
14 Nov 2002
Accepted
02 Jan 2003
First published
14 Jan 2003

Chem. Commun., 2003, 400-401

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C–H Activation of imidazolium salts by Pt(0) at ambient temperature: synthesis of hydrido platinum bis(carbene) compounds

M. A. Duin, N. D. Clement, K. J. Cavell and C. J. Elsevier, Chem. Commun., 2003, 400 DOI: 10.1039/B211235C

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