Jump to main content
Jump to site search

Issue 3, 2003
Previous Article Next Article

Preparation, structure, and some coordination properties of 2-chloro-3,3-diphenyl-3-thioxo-1-(2,4,6-tri-t-butylphenyl)-1,3-diphosphapropene

Author affiliations

Abstract

A sterically encumbered 3-thioxo-1,3-diphosphapropene, bearing a P[double bond, length as m-dash]C–P[double bond, length as m-dash]S skeleton, was prepared, characterised, and allowed to react with a carbonyltungsten(0) reagent and iodine affording the corresponding chelate tungsten(0) complex and charge-transfer complex with iodine, respectively, which were analysed by the X-ray crystallography.

Graphical abstract: Preparation, structure, and some coordination properties of 2-chloro-3,3-diphenyl-3-thioxo-1-(2,4,6-tri-t-butylphenyl)-1,3-diphosphapropene

Back to tab navigation

Supplementary files

Publication details

The article was received on 14 Nov 2002, accepted on 24 Dec 2002 and first published on 13 Jan 2003


Article type: Communication
DOI: 10.1039/B211230B
Chem. Commun., 2003, 398-399

  •   Request permissions

    Preparation, structure, and some coordination properties of 2-chloro-3,3-diphenyl-3-thioxo-1-(2,4,6-tri-t-butylphenyl)-1,3-diphosphapropene

    S. Ito, H. Liang and M. Yoshifuji, Chem. Commun., 2003, 398
    DOI: 10.1039/B211230B

Search articles by author

Spotlight

Advertisements