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Issue 4, 2003
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A novel cationic heteropolyoxovanadium(iv) cluster functionalized with organic ligands: synthesis and characterization of the fully reduced species [MnIIVIV6O6{(OCH2CH2)2N(CH2CH2OH)}6]Cl2

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Abstract

The solvothermal reaction of (HOCH2CH2)3N with [(n-C4H9)4N]3[H3V10O28] and MnCl2·4H2O in CH3CN and CH3OH yields a novel cationic heteropolyoxovanadium(IV) cluster, [MnIIVIV6O6{(OCH2CH2)2N(CH2CH2OH)}6]2+, containing a fully reduced new cyclic {MnV6N6O18} core with the Anderson structure.

Graphical abstract: A novel cationic heteropolyoxovanadium(iv) cluster functionalized with organic ligands: synthesis and characterization of the fully reduced species [MnIIVIV6O6{(OCH2CH2)2N(CH2CH2OH)}6]Cl2

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Article information


Submitted
14 Nov 2002
Accepted
17 Dec 2002
First published
15 Jan 2003

Chem. Commun., 2003, 532-533
Article type
Communication

A novel cationic heteropolyoxovanadium(IV) cluster functionalized with organic ligands: synthesis and characterization of the fully reduced species [MnIIVIV6O6{(OCH2CH2)2N(CH2CH2OH)}6]Cl2

M. I. Khan, S. Tabussum and R. J. Doedens, Chem. Commun., 2003, 532
DOI: 10.1039/B211195K

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