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Issue 3, 2003
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Direct preparation of polyfunctional amino-substituted arylmagnesium reagents via an iodine–magnesium exchange reaction

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Abstract

The successive addition of PhMgCl and i-PrMgCl to functionalised iodoanilines allows their conversion to the corresponding amino-functionalised Grignard reagents, which react smoothly with a range of electrophiles in high yield.

Graphical abstract: Direct preparation of polyfunctional amino-substituted arylmagnesium reagents via an iodine–magnesium exchange reaction

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Publication details

The article was received on 12 Nov 2002, accepted on 02 Jan 2003 and first published on 14 Jan 2003


Article type: Communication
DOI: 10.1039/B211115B
Chem. Commun., 2003, 396-397

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    Direct preparation of polyfunctional amino-substituted arylmagnesium reagents via an iodine–magnesium exchange reaction

    G. Varchi, C. Kofink, D. M. Lindsay, A. Ricci and P. Knochel, Chem. Commun., 2003, 396
    DOI: 10.1039/B211115B

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