Issue 2, 2003
From the journal:

Chemical Communications

Pd·Et3B-catalyzed alkylation of amines with allylic alcohols†

Masanari Kimura,*a   Makoto Futamata,a   Kazufumi Shibataa  and  Yoshinao Tamaru*a  

* Corresponding authors

a Department of Applied Chemistry, Faculty of Engineering, Nagasaki University, 1-14 Bunkyo-machi, Nagasaki, Japan
E-mail: masanari@net.nagasaki-u.ac.jp, tamaru@net.nagasaki-u.ac.jp
Fax: +81-95-847-9008
Tel: +81-95-847-9008

Abstract

A combination of catalytic amounts of Pd (0.05 mmol) and Et3B (0.3 mmol) promotes allylic alkylation of primary and secondary aromatic and aliphatic amines (1.0 mmol) by the direct use of allylic alcohols, providing tertiary amines in excellent yields under mild conditions (room temperature ∼50 °C).

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Article information

DOI
https://doi.org/10.1039/B210920D
Article type
Communication
Submitted
07 Nov 2002
Accepted
25 Nov 2002
First published
09 Dec 2002

Chem. Commun., 2003, 234-235

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Pd·Et3B-catalyzed alkylation of amines with allylic alcohols

M. Kimura, M. Futamata, K. Shibata and Y. Tamaru, Chem. Commun., 2003, 234 DOI: 10.1039/B210920D

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