Issue 13, 2003

The (butadiene)metal complex/B(C6F5)3 pathway to homogeneous single component Ziegler–Natta catalyst systems

Abstract

The Lewis acid B(C6F5)3 adds to a variety of (butadiene)metal systems to yield zwitterionic complexes that are active homogeneous Ziegler–Natta type olefin polymerization catalysts. The new compounds have been useful in experimental studies gaining information about details of the carbon–carbon coupling reactions at these often fast and selective catalyst systems.

Graphical abstract: The (butadiene)metal complex/B(C6F5)3 pathway to homogeneous single component Ziegler–Natta catalyst systems

Article information

Article type
Feature Article
Submitted
11 Sep 2002
Accepted
09 Jan 2003
First published
25 Apr 2003

Chem. Commun., 2003, 1469-1476

The (butadiene)metal complex/B(C6F5)3 pathway to homogeneous single component Ziegler–Natta catalyst systems

G. Erker, Chem. Commun., 2003, 1469 DOI: 10.1039/B208898N

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