Issue 6, 2003

Transition-metal-containing chiral bidentate ligands for enantioselective catalysis: non-metallocene architectural units come of age

Abstract

Structural and electronic properties associated with donor ligands that contain ‘spectator’ transition-metal fragments are analyzed. The current status of such non-ferrocenyl chiral bidentate ligands is reviewed from the standpoint of synthesis, applications in metal-catalyzed enantioselective reactions, and future directions.

Article information

Article type
Feature Article
Submitted
13 Aug 2002
Accepted
20 Sep 2002
First published
22 Oct 2002

Chem. Commun., 2003, 665-675

Transition-metal-containing chiral bidentate ligands for enantioselective catalysis: non-metallocene architectural units come of age

O. Delacroix and J. A. Gladysz, Chem. Commun., 2003, 665 DOI: 10.1039/B207963C

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