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Issue 24, 2002
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Mechanochemical assembly of hydrogen bonded organic-organometallic solid compounds

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Abstract

Solvent-free reactions with molecular systems have been exploited to prepare hybrid organic–organometallic solids: grinding of the complex [Fe(η5-C5H4COOH)2] with solid bases B generates quantitatively the corresponding hydrogen bonded salts [Fe(η5-C5H4COOH)(η5-C5H4COO)][HB] (B = 1,4-diazabicyclo[2.2.2]octane, 1,4-phenylenediamine); gas–solid reactions are also possible with volatile bases.

Graphical abstract: Mechanochemical assembly of hydrogen bonded organic-organometallic solid compounds

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Article information


Submitted
09 Oct 2002
Accepted
05 Nov 2002
First published
18 Nov 2002

Chem. Commun., 2002, 2960-2961
Article type
Communication

Mechanochemical assembly of hydrogen bonded organic-organometallic solid compounds

D. Braga, L. Maini, M. Polito, L. Mirolo and F. Grepioni, Chem. Commun., 2002, 2960
DOI: 10.1039/B209861J

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