Issue 24, 2002
From the journal:

Chemical Communications

Mechanochemical assembly of hydrogen bonded organic-organometallic solid compounds

Dario Braga,*a   Lucia Maini,a   Marco Polito,a   Laurent Miroloa  and  Fabrizia Grepioni*b  

* Corresponding authors

a Dipartimento di Chimica G. Ciamician, Università di Bologna, Via Selmi 2, 40126 Bologna, Italy
E-mail: dbraga@ciam.unibo.it

b Dipartimento di Chimica, Università di Sassari, Via Vienna 2, 07100 Sassari, Italy
E-mail: grepioni@ssmain.uniss.it

Abstract

Solvent-free reactions with molecular systems have been exploited to prepare hybrid organic–organometallic solids: grinding of the complex [Fe(η5-C5H4COOH)2] with solid bases B generates quantitatively the corresponding hydrogen bonded salts [Fe(η5-C5H4COOH)(η5-C5H4COO)][HB] (B = 1,4-diazabicyclo[2.2.2]octane, 1,4-phenylenediamine); gas–solid reactions are also possible with volatile bases.

Graphical abstract: Mechanochemical assembly of hydrogen bonded organic-organometallic solid compounds

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Article information

DOI
https://doi.org/10.1039/B209861J
Article type
Communication
Submitted
09 Oct 2002
Accepted
05 Nov 2002
First published
18 Nov 2002

Chem. Commun., 2002, 2960-2961

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Mechanochemical assembly of hydrogen bonded organic-organometallic solid compounds

D. Braga, L. Maini, M. Polito, L. Mirolo and F. Grepioni, Chem. Commun., 2002, 2960 DOI: 10.1039/B209861J

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