Synthesis of 2-silyl substituted phospharuthenocenes and an elaboration into the first phospharuthenocene-phosphine

Duncan Carmichael; François Mathey; Louis Ricard; Nicolas Seeboth

doi:10.1039/B208736G

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Synthesis of 2-silyl substituted phospharuthenocenes and an elaboration into the first phospharuthenocene-phosphine

Duncan Carmichael,*^a François Mathey,*^a Louis Ricard^a and Nicolas Seeboth^a

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* Corresponding authors

^a Laboratoire Hétéroéléments et Coordination, UMR CNRS 7653, DCPH Ecole Polytechnique, Palaiseau cedex, France
E-mail: Duncanc@mars.polytechnique.fr; francois.mathey@polytechnique.fr
Fax: +331 69333990

Abstract

A [1,5] shift protocol transiently hindering the 2-position of phospholide anions provides an access to sterically unencumbered phospharuthenocenes and the first phospharuthenocene-phosphine.

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Supplementary files

Crystal structure data TXT (37K)

Article information

DOI: https://doi.org/10.1039/B208736G
Article type: Communication
Submitted: 06 Sep 2002
Accepted: 24 Oct 2002
First published: 08 Nov 2002

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Chem. Commun., 2002, 2976-2977

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Synthesis of 2-silyl substituted phospharuthenocenes and an elaboration into the first phospharuthenocene-phosphine

D. Carmichael, F. Mathey, L. Ricard and N. Seeboth, Chem. Commun., 2002, 2976 DOI: 10.1039/B208736G

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Chemical Communications

Synthesis of 2-silyl substituted phospharuthenocenes and an elaboration into the first phospharuthenocene-phosphine

Abstract

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Synthesis of 2-silyl substituted phospharuthenocenes and an elaboration into the first phospharuthenocene-phosphine

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