Issue 20, 2002
From the journal:

Chemical Communications

Catalytic enantioselective intermolecular [2 + 2 + 2] cycloaddition of an alkene and two alkynes†

Shin-ichi Ikeda,*a   Hirokazu Kondo,a   Taro Ariia  and  Kazunori Odashimaa  

* Corresponding authors

a Graduate School of Pharmaceutical Sciences, Nagoya City University, Tanabe-dori, Mizuho-ku, Nagoya 467-8603, Japan
E-mail: ikeshin@phar.nagoya-cu.ac.jp

Abstract

A catalytic enantioselective intermolecular [2 + 2 + 2] cycloaddition of one molecule of alkene (enone) and two molecules of alkyne was developed in the presence of a nickel complex modified by chiral monodentate oxazoline ligands, which have not previously been used as chiral ligands for transition metals in asymmetric catalysts, and an aluminium phenoxide.

Graphical abstract: Catalytic enantioselective intermolecular [2 + 2 + 2] cycloaddition of an alkene and two alkynes

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Article information

DOI
https://doi.org/10.1039/B208313B
Article type
Communication
Submitted
27 Aug 2002
Accepted
09 Sep 2002
First published
20 Sep 2002

Chem. Commun., 2002, 2422-2423

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Catalytic enantioselective intermolecular [2 + 2 + 2] cycloaddition of an alkene and two alkynes

S. Ikeda, H. Kondo, T. Arii and K. Odashima, Chem. Commun., 2002, 2422 DOI: 10.1039/B208313B

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