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Issue 19, 2002
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First determination of the absolute stereochemistry of a naturally occurring 1,1′-biphenanthrene, (−)-blestriarene C, and its unexpected photoracemization

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Abstract

A naturally occurring 1,1′-biphenanthrene, blestriarene C, was prepared and its absolute stereochemistry was determined to be Sa-(−) by an empirical method, during which the compound was found to undergo rapid photoracemization even under ambient light exposure.

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Publication details

The article was received on 01 Aug 2002, accepted on 23 Aug 2002 and first published on 06 Sep 2002


Article type: Communication
DOI: 10.1039/B207517B
Chem. Commun., 2002, 2234-2235

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    First determination of the absolute stereochemistry of a naturally occurring 1,1′-biphenanthrene, (−)-blestriarene C, and its unexpected photoracemization

    T. Hattori, Y. Shimazumi, O. Yamabe, E. Koshiishi and S. Miyano, Chem. Commun., 2002, 2234
    DOI: 10.1039/B207517B

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