Jump to main content
Jump to site search

Issue 20, 2002
Previous Article Next Article

Syntheses and structures of an unsolvated tetrakisimidophosphate {Li3[P(NBut)3(NSiMe3)]}2 and the face-sharing double-cubane {Li2(THF)[P(O)(NBut)2(NHBut)]}2

Author affiliations

Abstract

The treatment of Me3SiN[double bond, length as m-dash]P(NHBut)3 with three equivalents of LiBun in toluene produces {Li3[P(NBut)3(NSiMe3)]}2 comprised of a Li6N6 cyclic ladder capped on the two hexagonal faces by μ3-PNSiMe3 groups; the corresponding reaction of O[double bond, length as m-dash]P(NHBut)3 yields the face-sharing double-cubane {Li2(THF)P(O)(NBut)2(NHBut)}2 with a central Li2O2 ring.

Graphical abstract: Syntheses and structures of an unsolvated tetrakisimidophosphate {Li3[P(NBut)3(NSiMe3)]}2 and the face-sharing double-cubane {Li2(THF)[P(O)(NBut)2(NHBut)]}2

Back to tab navigation

Supplementary files

Article information


Submitted
24 Jul 2002
Accepted
28 Aug 2002
First published
13 Sep 2002

Chem. Commun., 2002, 2332-2333
Article type
Communication

Syntheses and structures of an unsolvated tetrakisimidophosphate {Li3[P(NBut)3(NSiMe3)]}2 and the face-sharing double-cubane {Li2(THF)[P(O)(NBut)2(NHBut)]}2

A. Armstrong, T. Chivers, M. Krahn, M. Parvez and G. Schatte, Chem. Commun., 2002, 2332 DOI: 10.1039/B207197E

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.


Social activity

Search articles by author

Spotlight

Advertisements