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Issue 21, 2002
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A new synthetic method to Mn carboxylate clusters: reductive fragmentation of [Mn12O12(O2CR)16(H2O)4] to [Mn8O2(O2CR)14(RCO2H)4] (R = CH2But)

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Abstract

The reaction of [Mn12O12(O2CCH2But)16(H2O)4] (1) with a reducing agent followed by recrystallization from CH2Cl2/MeNO2 affords the novel octanuclear complex [Mn8O2(O2CCH2But)14(ButCH2CO2H)4] (2).

Graphical abstract: A new synthetic method to Mn carboxylate clusters: reductive fragmentation of [Mn12O12(O2CR)16(H2O)4] to [Mn8O2(O2CR)14(RCO2H)4] (R = CH2But)

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Article information


Submitted
14 Jul 2002
Accepted
12 Sep 2002
First published
27 Sep 2002

Chem. Commun., 2002, 2502-2503
Article type
Communication

A new synthetic method to Mn carboxylate clusters: reductive fragmentation of [Mn12O12(O2CR)16(H2O)4] to [Mn8O2(O2CR)14(RCO2H)4] (R = CH2But)

C. Boskovic, J. C. Huffman and G. Christou, Chem. Commun., 2002, 2502
DOI: 10.1039/B206751J

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