Issue 19, 2002
From the journal:

Chemical Communications

C-Phosphanyl-C-chloroiminium salts as electrophilic carbene synthetic equivalents

Nathalie Merceron,a   Antoine Baceiredo,a   Heinz Gornitzkaa  and  Guy Bertrand*ab  

* Corresponding authors

a Laboratoire Hétérochimie Fondamentale et Appliquée du CNRS (UMR 5069), Université Paul Sabatier, 118, route de Narbonne, Toulouse Cedex 04, France

b UCR-CNRS Joint Research Chemistry Laboratory (UMR 2282) Department of Chemistry, University of California, Riverside, CA, USA
E-mail: gbertran@mail.ucr.edu
Fax: (1)-9097872725

Abstract

C-Phosphanyl-C-chloroiminium salts formally react as phosphonio(amino)carbenes with tert-butyl isocyanide and trimethylphosphine, and as R2NC+ with vinyl ether and diisopropylamine.

Graphical abstract: C-Phosphanyl-C-chloroiminium salts as electrophilic carbene synthetic equivalents

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Article information

DOI
https://doi.org/10.1039/B206641F
Article type
Communication
Submitted
10 Jul 2002
Accepted
22 Aug 2002
First published
09 Sep 2002

Chem. Commun., 2002, 2250-2251

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C-Phosphanyl-C-chloroiminium salts as electrophilic carbene synthetic equivalents

N. Merceron, A. Baceiredo, H. Gornitzka and G. Bertrand, Chem. Commun., 2002, 2250 DOI: 10.1039/B206641F

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