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Issue 19, 2002
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C-Phosphanyl-C-chloroiminium salts as electrophilic carbene synthetic equivalents

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Abstract

C-Phosphanyl-C-chloroiminium salts formally react as phosphonio(amino)carbenes with tert-butyl isocyanide and trimethylphosphine, and as R2NC+ with vinyl ether and diisopropylamine.

Graphical abstract: C-Phosphanyl-C-chloroiminium salts as electrophilic carbene synthetic equivalents

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Supplementary files

Article information


Submitted
10 Jul 2002
Accepted
22 Aug 2002
First published
09 Sep 2002

Chem. Commun., 2002, 2250-2251
Article type
Communication

C-Phosphanyl-C-chloroiminium salts as electrophilic carbene synthetic equivalents

N. Merceron, A. Baceiredo, H. Gornitzka and G. Bertrand, Chem. Commun., 2002, 2250
DOI: 10.1039/B206641F

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