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Issue 20, 2002
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Linear alignment of four sulfur atoms in bis[(8-phenylthio)naphthyl] disulfide: contribution of linear S4 hypervalent four-centre six-electron bond to the structure

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Abstract

The four sulfur atoms in bis[8-(phenylthio)naphthyl]-1,1′-disulfide are demonstrated to align linearly by the X-ray crystallographic analysis, where the linear S4 alignment is stabilized by the four-centre six-electron interaction.

Graphical abstract: Linear alignment of four sulfur atoms in bis[(8-phenylthio)naphthyl] disulfide: contribution of linear S4 hypervalent four-centre six-electron bond to the structure

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Supplementary files

Article information


Submitted
26 Jun 2002
Accepted
10 Sep 2002
First published
25 Sep 2002

Chem. Commun., 2002, 2416-2417
Article type
Communication

Linear alignment of four sulfur atoms in bis[(8-phenylthio)naphthyl] disulfide: contribution of linear S4 hypervalent four-centre six-electron bond to the structure

W. Nakanishi, S. Hayashi and T. Arai, Chem. Commun., 2002, 2416
DOI: 10.1039/B206137F

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