Issue 20, 2002
From the journal:

Chemical Communications

Linear alignment of four sulfur atoms in bis[(8-phenylthio)naphthyl] disulfide: contribution of linear S4 hypervalent four-centre six-electron bond to the structure

Warô Nakanishi,*a   Satoko Hayashia  and  Takamitsu Araia  

* Corresponding authors

a Department of Material Science and Chemistry, Faculty of Systems Engineering, Wakayama University, 930 Sakaedani, Wakayama 640-8510, Japan
E-mail: nakanisi@sys.wakayama-u.ac.jp
Fax: +81 73 457 8253
Tel: +81 73 457 8252

Abstract

The four sulfur atoms in bis[8-(phenylthio)naphthyl]-1,1′-disulfide are demonstrated to align linearly by the X-ray crystallographic analysis, where the linear S4 alignment is stabilized by the four-centre six-electron interaction.

Graphical abstract: Linear alignment of four sulfur atoms in bis[(8-phenylthio)naphthyl] disulfide: contribution of linear S4 hypervalent four-centre six-electron bond to the structure

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/B206137F
Article type
Communication
Submitted
26 Jun 2002
Accepted
10 Sep 2002
First published
25 Sep 2002

Chem. Commun., 2002, 2416-2417

Permissions

Request permissions

Linear alignment of four sulfur atoms in bis[(8-phenylthio)naphthyl] disulfide: contribution of linear S4 hypervalent four-centre six-electron bond to the structure

W. Nakanishi, S. Hayashi and T. Arai, Chem. Commun., 2002, 2416 DOI: 10.1039/B206137F

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements