Issue 16, 2002
From the journal:

Chemical Communications

A total synthesis of phomactin A†

William P. D. Goldringa  and  Gerald Pattenden*a  

* Corresponding authors

a School of Chemistry, The University of Nottingham, University Park, Nottingham, UK
E-mail: gp@nottingham.ac.uk
Fax: +44 (0)115 951 3535
Tel: +44 (0)115 951 3530

Abstract

A total synthesis of phomactin A (1) based on a Cr(II)/Ni(II) macrocyclisation from the aldehyde vinyl iodide 11, leading to 12, followed by elaboration of the epoxyketone 16, which then undergoes spontaneous pyran-hemiacetal formation on deprotection, is described.

Graphical abstract: A total synthesis of phomactin A

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Article information

DOI
https://doi.org/10.1039/B206041H
Article type
Communication
Submitted
21 Jun 2002
Accepted
01 Jul 2002
First published
11 Jul 2002

Chem. Commun., 2002, 1736-1737

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A total synthesis of phomactin A

W. P. D. Goldring and G. Pattenden, Chem. Commun., 2002, 1736 DOI: 10.1039/B206041H

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